[pure-silver] Re: Adding Pot Bromife to PC-TEA

  • From: "John Black" <jblack@xxxxxxxxx>
  • To: <pure-silver@xxxxxxxxxxxxx>
  • Date: Thu, 6 Jan 2005 13:01:58 -0500


> I was testing a new lens on one of my Nikons.  The film was 35mm Eastman
5231
> ISO 80 rated at an EI of 125 and developed in the following developer
(diluted)
> 1+49 for 8 minutes at 22 C.
>
> Propylene glycol .......................  50.0  ml
> Triethanolamine ........................  50.0  ml
> Ascorbic acid ..........................   9.0  g
> Dimezone-S .............................   0.3  g
> Potassium bromide ......................   0.25 g
>
> Without the bromide there was an objectionable amount of fog and it was
> difficult to obtain sufficient contrast without too much density.


Hmmm....  My PC-TEA used G's recommended concentration of TEA that has twice
as much as this. I dispersed (can't really use the term dissolved) the P and
C in 100ml TEA with no PrGL.  I was put off by the viscous nature of the TEA
so I thinned it out 1:1 with dry methanol. The resultant mixture I diluted
1:25 for use.  Your modification cuts the TEA in half, which should be fine
as it is somewhat in excess in G's formulas.

I agree that the unmodified PC/TEA as per Gainer gives some fog but is quite
active and shows a good CI and speed.  In my hands, though, it is grainier
than I would like (yes, I'm probably too anal about it) resulting from a
higher pH than I would like.  If you dilute the PC/TEA in water that has 5/5
(gm/L) sulfite/boric acid, the pH come down and the fog disappears.  All
this is for 35mm though, and I would not hesitate to use the unmodified
Gainer formulations for RF and LF.

BTW, my TEA is reagent grade from Sigma so it should behave normally.

JB




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