[pure-silver] Re: D-76 and variations

  • From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx>
  • To: <pure-silver@xxxxxxxxxxxxx>
  • Date: Tue, 29 Nov 2005 12:14:05 -0800


----- Original Message ----- From: "Nick Zentena" <zentena@xxxxxxxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Tuesday, November 29, 2005 11:37 AM
Subject: [pure-silver] Re: D-76 and variations



On Tuesday 29 November 2005 14:15, Koch, Gerald wrote:

still see this chesnut spouted as gospel on the web. Strictly speaking
only D-76 is D-76 but I am willing to consider all developers that are
similar even D-76H.


But packaged Kodak D-76 isn't D-76 is it?

Nick


It is. Its approximately the same as the buffered version in the paper by Carlton and Crabtree of Kodak Labs published in 1929. D-76 was originally formulated by John Capstaff, of Kodak Labs and announced in a booklet (1926) describing a new film for duplicating motion picture negatives. It became popular for processing the negatives themselves. It was one of the first developers to be formulated on the basis of any scientific knowledge of chemistry.
Evidently, the rise in activity became evident quickly. Consistency is important in motion picture processing because negatives made at different times must be intercut. Carlton and Crabtree undertook an extensive investigation of D-76. In the paper they report on something like 30 variations. The one which is recommended is D-76 with the inclusion of a buffer system. Kodak called this formula D-76d. As a matter of interest there was also a D-76c but that was devised later for low contrast development of scientific plates. D-76, D-76d, D-76c, and DK-76, the Kodalk version, are AFAIK the only D-76 developers devised by Kodak. Plenty of other M-H Borax developers were devised by others. Most of these were for use in automatic developing machines for motion pictures. Kodak's current developer for this purpose is D-96 which is similar to D-76 but with different ratios of developing agents. It might be of some interest.


Kodak D-96
Water (125F or 52C)                750.0 ml
Metol                                1.5 grams
Sodium sulfite, dessicated          75.0 grams
Hydroquinone                         1.5 grams
Potassium bromide                    0.4 grams
Borax, granulated (decahydrated)     4.5 grams
Water to make                        1.0 liter

Recommendation for current Plus-X motion picture stock (not the same film as Plus-X still film) is 5 minutes at 70F in a continuous machine for a gamma of 0.65 to 0.70

The paper I keep refering to is:

"Some Properties of Fine-Grain Developers for Motion Picture Film", H.C.Carlton and J.I.Crabtree
_Transactions of the Society of Motion Picture Engineers_ Vol XIII, No.38, 1929 (p.406)
See also:
"Borax Developer Characteristics", H.W.Moyse and D.R.White, (DuPont Labs) loc.cit. p.445



---
Richard Knoppow
Los Angeles, CA, USA
dickburk@xxxxxxxxxxxxx


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