[pure-silver] Re: disposing of developer and fixer in rural areas

  • From: shannon Stoney <shannonstoney@xxxxxxxxxxxxxxx>
  • To: pure-silver@xxxxxxxxxxxxx
  • Date: Wed, 10 Oct 2012 15:04:44 -0500

Presumably this sludge also had some developer chemicals in it, such as metol 
or hydroquinone?


On Oct 10, 2012, at 2:13 PM, Ken Sinclair wrote:

> Many years ago….
> 
> About 50 or so, My mentor would pour his used fixer into a carboy… to which 
> he would then pour in used paper 
> developer that still had some 'life' left. 
> 
> After a few months there would be a 'dark sludge' lying at the bottom of his 
> 'capped' carboy.
> 
> The carboy was put up on the table top and the clear liquid syphoned off to a 
> few inches above the 'sludge'.
> 
> Every now and again, he would add some water, stir to get the 'sludge' well 
> mixed….  and again slowly syphon off 
> the liquid into another carboy (through a number of paper filters in a filter 
> funnel). This collected sludge was allowed
> to dry and the  'black powder' was given to a friend (a chemistry prof at the 
> university).
> 
> 'Somewhere' in a box down in the basement, I still have a 'chunk' of what I 
> was told was some of the recovered silver.
> 
> I am not sure if, or what, further processing was done to the extracted black 
> powder but I was told it was heated in a 
> muffle furnace
> 
> 
> That 'might' be a means of curing or at least  reducing possible silver 
> contamination the sewage system.
> 
> 
> Ken
> 
> On 2012-10-10, at 12:30 PM, John Bower <john@xxxxxxxxxxxxxxxxx> wrote:
> 
>> I too am on a septic system, and I asked a lot of questions, and thought 
>> about this a lot. Here's what I've decided to do:
>> 
>> I pour the used stop bath into the used developer, which yields a relatively 
>> neutral pH. Then I pour it all down the drain. In general, it seems no worse 
>> than many household chemicals that people use, and really isn't that much 
>> volume.
>> 
>> I'm more worried about the silver in the spent fixer "poisoning" the 
>> bacteria in the septic tank. So, I made an outdoor evaporation tray to put 
>> it in. It consists of a wood frame with a large darkroom tray (mounted 
>> level), and a hinged cover to keep rain out. There's a screen stapled around 
>> the perimeter to keep critters out. I just pour the spent fixer into the 
>> tray and the liquid (mostly water) evaporates after a while, leaving some 
>> crud on the bottom of the tray.
>> 
>> I've been doing this for 10 years and I have my septic tank pumped out every 
>> three years (a good idea in any case, as preventive medicine) and each time 
>> it's pumped out I ask the guy if it seems "healthy." I don't know if he can 
>> tell healthy from unhealthy, but he's always said it seems just fine.
>> 
>> Sooner or later, I will need to do something about the silver-laden residue 
>> in the evaporation tray. My local recycling center will take spent fixer, 
>> but they charge more than the cost of new fixer. So, in another 10 years, I 
>> will mix the residue into some spent fixer, take it to them, and pay them 
>> for a gallon's worth. If they pass it on to a reprocessor who recovers the 
>> silver, they will get a good deal because there should be a decent amount of 
>> silver in it by then.
>> --
>> John Bower, an Indiana Artisan
>> http://www.studioindiana.com/
>> 
>> 
>> 
>> On Oct 10, 2012, at 1:34 PM, shannon Stoney wrote:
>> 
>>> I just moved my darkroom to rural TN this summer and now it's ready to go. 
>>> But I'm trying to figure out how to dispose of used developer and fixer. I 
>>> have a septic system, and the little bit of research I've done today 
>>> indicates that I shouldn't just put it into the septic system (according to 
>>> Kodak). I just called the Solid Waste people here in Putnam County, and 
>>> they are going to look into it for me, but they didn't really know what I 
>>> was talking about and I have the feeling they are going to say, "We can't 
>>> deal with this." So what would be another option?
>>> 
>>> -- 
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