[pure-silver] Re: Citric Acid as stop bath

  • From: Laurence cuffe <cuffe@xxxxxx>
  • To: pure-silver@xxxxxxxxxxxxx
  • Date: Sat, 16 Oct 2010 16:07:39 +0000


On 16 Oct 2010, at 15:54, Gerald Koch wrote:

Phenol was once used for cosmetic face peels, it was applied to the skin full strength. At this concentration it can cause systemic poisoning, but dilute solutions are relatively safe. I have used various throat sprays, gargles, etc. containig it without any problem. Remember menthol is a phenol and people consume it every day in various forms such as peppermint.

"It is not only the poison it is also the dosage."
Jerry
Quoting from the source cited previously
"All forms of phenol cause irritation, and acute toxic effects of phenol most often occur by skin contact. Even dilute solutions (1% to 2%) may cause severe burns if contact is prolonged." I'm not one of the school that believe that all chemicals are bad, my Ph.D. is in chemistry, and I'm not a toxicologist. but this is a case where I would be a little careful. there is a potential for liver damage after absorbtion through the skin, and while many photographers have a reasonable attitude to darkroom safety, some are likely to spend very long hours up to their arms in solutions dedicated to "getting a real feel for their art" My favorite source for a good safety attitude is Henry "controls in B&W photography". This reference may need correction as I'm not quite sure where my copy is after a number of transoceanic relocations.
All the best
LArry Cuffe
From: Laurence cuffe <cuffe@xxxxxxx>
To: pure-silver@xxxxxxxxxxxxx
Sent: Sat, October 16, 2010 10:42:01 AM
Subject: [pure-silver] Re: Citric Acid as stop bath

I know when I was supervising second year Organic Chemistry practicalls, phenol was considered to be one of the nastiest chemicals we had to handle. Skin burns can be very difficult to treat. We often confuse familiarity with safety. Common salt, and petrol (gas) are two common chemicals I use when looking for a benchmark to compare safety information on a chemical with. On this comparison phenol comes out on the nasty side.
There is some fairly comprehensive information here:
http://www.atsdr.cdc.gov/mhmi/mmg115.html
I was particularly struck by this piece:
Phenol vapor and liquid penetrate the skin with an absorption efficiency approximately equal to the absorption efficiency by inhalation. In one case, death occurred within 30 minutes after skin contact.
All the best and have fun!
Laurence Cuffe
On 16 Oct 2010, at 00:42, Richard Knoppow wrote:


----- Original Message ----- From: <mark@xxxxxxxxxxxxxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Friday, October 15, 2010 3:26 PM
Subject: [pure-silver] Re: Citric Acid as stop bath


Richard that sounds like the voice of experience there. There would have been days I would have loved to have dealt with the taste of Lifeboy, but that wasn't mom. When she was really mad, she would send you out to get your own switch.

Turns out its Lifebouy. I think the carbolic acid in it would have been worse even than the Stodard solvent in Fels Naptha. My mom would not allow Lifebouy in the house, partly because of its odor and partly because it would take your skin right off. It was popular in institutions because of its claimed antiseptic properties. I think the phenol was pretty toxic. We did have Fels Naptha, it was used strictly for difficult laundry. Fels Naptha is still made but no longer has Stodard Solvent in it but Lifebouy with carbolic is evidently still on the market in some parts of the world. The Lifebouy radio commercials featured a vocalized fog horn effect, the key line was "Why have BEEE OHHHH, with the BO vocalized with the fog horn. There was at the time a machine for producing speaking sound effects, I have forotten the name of it. It was used for Bromo-Seltzer commercials with the sound of a locomotive and was the effect used in the movie "Letter to Three Wives". I think it was also used for the Lifebouy commercial but its been so long since I've heard it I can't be sure. Not to be confused with the deoderant that advertised "Don't be half-safe" I can't remember what that was either.


--
Richard Knoppow
Los Angeles
WB6KBL
dickburk@xxxxxxxxxxxxx
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