[pure-silver] Re: holes in emulsion and temperature

  • From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx>
  • To: <pure-silver@xxxxxxxxxxxxx>
  • Date: Wed, 5 Dec 2007 14:19:51 -0800


----- Original Message ----- From: "Shannon Stoney" <shannonstoney@xxxxxxxxxxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Wednesday, December 05, 2007 2:06 PM
Subject: [pure-silver] holes in emulsion and temperature



It suddenly occurred to me today that maybe the holes in the emulsion of my recent negatives (120 roll film) might have happened because the stop could have been colder than the developer. Could that be a factor? My darkroom is in the garage and sometimes in winter the solutions get pretty cold out there, even in Houston. I make sure the developer is warm, of course, but I don't worry too much about the stop and fix. But maybe when the cold stop hits the warmer negative, it has a bad effect on it. Could this be the case?

--shannon

Some very old books advise having all solutions exactly the same temperature but this is a left-over from the 1920s when emulsions were very soft and tended to reticulate (wrinkle) is subjected to much temperature variation or to even moderate temperatures. Modern films are very hard in comparision, in fact, some, like the T-Max series, are hardened like color films to withstand 100F processing. In any case a couple of degrees difference in temperature will make no difference. Nor will gas generation in the stop bath cause pin-holes for the same reason. In addition, gas is generated only if the developer contains a carbonate and most modern developers do not. The consern in the old days was mostly about reticulation, not pin holes. Its very hard to reticulate modern film even for a special effect.

---
Richard Knoppow
Los Angeles, CA, USA
dickburk@xxxxxxxxxxxxx
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