[pure-silver] Re: WORKING OR STOCK? Darkroom Chemistry... Question

  • From: `Richard Knoppow <dickburk@xxxxxxxxxxxxx>
  • To: pure-silver@xxxxxxxxxxxxx
  • Date: Tue, 03 Mar 2015 22:50:21 -0800



On 3/3/2015 1:04 PM, Brian Smith (Redacted sender smithcbrian2@xxxxxxxxx for DMARC) wrote:
Thanks Richard for you very informative reply on fixers. Given that I don't use a hardening agent (and ignoring any minerals in the wash water), could I omit the EDTA from HCA without affecting its pH? Regards - Brian

I don't think the sequestering agents have much effect on the pH. They are mainly meant to prevent sludging from aluminum compounds from the fixer and probably magnesium from the wash water. I think they are also added so that the wash aid can be reused. I generally use it one-shot. I posted the citations to Kodak's technical papers and the patent long ago but would have to search through my records to find them. BTW, Kodak did an enormous amount of research on fixing and washing. Much of this stuff was published in more than one place, often the Journal of the Society of Motion Picture Engineers. When the labs were created in 1912 Meese and associates decided that their scientific and technical papers should be published in established peer-reviewed journals rather than in a house organ. This gave Kodak's papers an immediate prestige they would not otherwise have had.

--
Richard Knoppow
dickburk@xxxxxxxxxxxxx
WB6KBL

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