[pure-silver] Re: Seasoning a developer - cream without sediment

  • From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx>
  • To: <pure-silver@xxxxxxxxxxxxx>
  • Date: Sun, 7 Feb 2010 07:11:54 -0800


----- Original Message ----- From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Saturday, February 06, 2010 1:42 PM
Subject: [pure-silver] Re: Seasoning a developer - cream without sediment



----- Original Message ----- From: "Nicholas O. Lindan" <nolindan@xxxxxxxxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Friday, February 05, 2010 8:57 PM
Subject: [pure-silver] Re: Seasoning a developer - cream without sediment


"Nicholas O. Lindan" <nolindan@xxxxxxxxxxxxx>

There was a method of getting to this point with a fresh batch of developer
by 'seasoning' it.

Should have done some research before posting.

There are several discussions on this topic in the google groups archives
for rec.photo.darkroom, search for <seasoned developer>

It seems the seasoned effect is due to a build up of bromide and silver. The bromide buildup can be achieved by adding .7 g/l of P. Bromide to D-76, don't know what the amount would be with Xtol. Don't know about the silver salts - is there some way to get them out of used
hypo?

==
Nicholas O. Lindan
Cleveland Engineering Design, LLC
Cleveland, Ohio 44121

For B&W developers its mostly bromide, I am not sure what else is in "developer starters" for color. Some of the residue in replenished developers is gelatin from the film. Some may be precipitated minerals from the water. The developer should be filtered occasionally to prevent deposits of junk on the film. A coffee filter or a wad of cotton in a funnel works fine. Very large developing plants, like motion picture labs, recover silver from all solutions by electrolytic means. This is both to recycle the silver and to extend the life of the solutions. The methods are covered in the technical literature but I no longer remember specific detail. Electrolytic regeneration of hypo seem to me to go back a very long time. In color work virtually all the silver in the emulsion is removed during processing to the amount that can be recovered is considerable and generally is worth enough to pay for the recovery. Note that at large labs the processing solutions also undergo continuous chemical analysis as part of keeping the processing consistent.

--
Richard Knoppow
Los Angeles, CA, USA
dickburk@xxxxxxxxxxxxx
    Having  read this later...
The old idea of seasoning is to add some used developer to fresh stock. Whatever accumulates in the developer is then carried over in some small amount. AFAIK, there is no fixed rule for this. It makes sense for continuous machines or replenished systems. The seasoning will affect the film curve somewhat and of course will reduce film speed just a bit. However, it may also reduce grain a bit too.

--
Richard Knoppow
Los Angeles, CA, USA
dickburk@xxxxxxxxxxxxx
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