[pure-silver] Re: Mixing My Own Fixer

  • From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx>
  • To: <pure-silver@xxxxxxxxxxxxx>
  • Date: Mon, 25 Oct 2010 11:03:03 -0700


----- Original Message ----- From: <JS2RT@xxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Monday, October 25, 2010 6:59 AM
Subject: [pure-silver] Re: Mixing My Own Fixer


I'm confused about how much ammonium thiosulfate to use when converting a formula that originally had sodium thiosulfate. For example if the original formula called for 240 grams of crystalline sodium thiosulfate I multiply the 240 grams by the ratio of the molecular weights to get the new amounts. If I am using anhydrous sodium thiosulfate I multiply by 158/248 and get 153 grams of anhydrous sodium thiosulfate. If I want to use ammonium thiosulfate in powder form I multiply by 148/248 and get 143 grams of powdered
ammonium thiosulfate.

As I understand it a 60% solution of liquid ammonium thiosulfate has 60 grams of the chemical per 100 ml of the solution. So I divide the 143 grams I need by 60 grams/100 ml and come up with 238 ml of the 60% solution as being equivalent with the original 240 grams of crystalline sodium thiosulfate.

Are my calculations correct?

That sounds correct. This is for a working solution. Ammonium thiosulfate will dissolve in much greater quantity than sodium thiosulfate so one can make up concentrated stock solutions if desired. For a working solution its interesting that the amount of 60% ammonium thiosulfate in milliliters is essentially the same as the amount of sodium thiosulfate, crystalline, in grams.

--
Richard Knoppow
Los Angeles, CA, USA
dickburk@xxxxxxxxxxxxx
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