[AR] Re: "Direct" Hydrogen Peroxide engines

  • From: Henry Vanderbilt <hvanderbilt@xxxxxxxxxxxxxx>
  • To: arocket@xxxxxxxxxxxxx
  • Date: Fri, 16 Sep 2016 07:18:51 -0700

As I read the earlier post, the failure was not in the platinum/palladium coating but in the underlying ceramic beads. Automotive cat converters heat up and cool down relatively gradually so surviving extreme thermal shock probably isn't a design requirement for the catalyst's ceramic substrate. (Extreme parsimony with the actual catalyst metals definitely is a design requirement.)

Just out of curiosity, anyone have a source and price on pure platinum/palladium mesh or wire? On plated mesh or wire? It occurs to me that it might be overall cheaper to bite the bullet and pay, say, $10K per engine, than to put more time and effort into finding a cheap alternative for HTP cat-packs when that's already soaked up so much time and effort to no avail.

Henry

On 9/16/2016 5:14 AM, William Claybaugh wrote:

Randall:

Very clever, raiding catalytic converters.  I'll look into exactly what
the car companies use; pure platinum / palladium should not have failed
at peroxide temps....

Just curious and OT, but could you see more than a bright dot?  Wings?

Bill

On Friday, September 16, 2016, Randall Clague <rclague@xxxxxxxxx
<mailto:rclague@xxxxxxxxx>> wrote:

    Hi Bill,

    Not hardly; these were platinum/palladium beads scavenged from a
    catalytic converter at a junkyard. Considering the difference in
    mass flow between what they were designed to handle and what ERPS
    asked of them, it's no wonder they were pulverized.  It's a tribute
    to automotive engineering that they worked for as long as they did
    under those conditions.

    I didn't know that about X-37, thanks.  I did see one in flight.
    10x50s from a Burbank back yard. 22 Dec 11, so that would have been
    OTV-2.

    -R


    On Thu, Sep 15, 2016 at 1:33 PM, William Claybaugh
    <wclaybaugh2@xxxxxxxxx
    <javascript:_e(%7B%7D,'cvml','wclaybaugh2@xxxxxxxxx');>> wrote:

        Randall:

        I deduce from your discription that the Platimium / Palladium
        was deposited on some sort of matrix and that the coating came
        off under differential thermal expansion; yes?

        The 98% peroxide thrusters developed--but not used--for X-37
        used woven screens in more or less the conventional manner used
        for silver.  They worked w/o incident in testing.

        Bill


        On Thursday, September 15, 2016, Randall Clague
        <rclague@xxxxxxxxx
        <javascript:_e(%7B%7D,'cvml','rclague@xxxxxxxxx');>> wrote:

            ERPS tested platinum/palladium beads in 1994.  The beads
            work fine in an ashtray, as ERPS demonstrated during their
            talks at Space Access '94 and '95.  (In '95 they scorched
            the tablecloth, and they were asked not to repeat their
            demonstration.)

            Video of a test ERPS did with a platinum/palladium bead
            catalyst pack shows that the exhaust starts out white, goes
            clear, then turns tan.  Post-test inspection showed that
            many beads were crushed or absent.  The tan exhaust was
            interpreted as pulverized catalyst departing the engine, and
            their hypothesis was that the beads lost structural
            integrity due to thermal shock.

            -R

            On Wed, Aug 24, 2016 at 11:46 PM, William Claybaugh
            <wclaybaugh2@xxxxxxxxx> wrote:

                I'm pretty sure that Platinum / Palladium cat beds are
                proven to work just fine and last forever running 98%
                Peroxide.

                Bill




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