[pure-silver] Re: toning the new Adox MCC 110

  • From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx>
  • To: <pure-silver@xxxxxxxxxxxxx>
  • Date: Sat, 24 Jul 2010 18:31:09 -0700


----- Original Message ----- From: "Dennis P" <dlp4777@xxxxxxxxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Saturday, July 24, 2010 11:39 AM
Subject: [pure-silver] Re: toning the new Adox MCC 110



On Jul 24, 2010, at 11:23 AM, Richard Knoppow wrote:

Bromide in the developer can affect the image color, usually the more bromide the finer the crystals and the more yellow the color. However, Ira Current, of Ansco, found that very large amounts of bromide added to the developer would _cool_ the tone given by bleach and redevelop Sepia toner, its described in his patent USP 2,607,686. Its also true that the emulsion has a strong effect on the color produced by a toner, for instance, the polysulfide toners (like Kodak Brown Toner) now recommended for protection of microfilm images will produce a sepia color on most printing paper but results in a blue shift on microfilm which has a very fine
grain structure.

--


So you are saying that using more Potassium Bromide in the developer makes the print color warmer because it makes the silver crystals smaller. Is that the same as to say that Potassium Bromide makes a finer grained print? Would that be the same case in processing more normal films (than microfilm)? It will make a finer grained negative?
thanks
Dennis

Bromide is a fine grain agent but it also reduces speed significantly. This is not so important in paper but is for film and there are better ways to get fine grain development for film. An important fine grain agent not mentioned much in the literature is sodium chloride (table salt). This is the main ingredient in Microdol-X and Perceptol. In general the use of large amounts of bromide in film developers is discouraged because it tends to destroy part of the latent image. I don't know the theory of Ira Current's discovery, of course it is somewhat the opposite of what the original poster wanted, namely stronger red-brown effects from Selenium toner. Indirect toner, the bleach and redevelop kind, tends to produce too yellow a color on warm tone paper. What Current found was than by adding very large amounts of bromide to an active developer warm tone paper could be toned to a "cool" or bluish brown with indirect toner. I have never tried this but it comes from a reliable source and probably works. At the time Ansco made a number of originally AGFA papers including a couple of very warm toned ones like Indiatone so such a method might have been valuble to them.

--
Richard Knoppow
Los Angeles, CA, USA
dickburk@xxxxxxxxxxxxx
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