From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx> Subject: [pure-silver] Re: PMK was Re: Tri X film versions and sizes Date: Wed, 16 Feb 2005 17:15:04 -0800 > What do you mean by "intension"? I meant intention. > I was NOT suggesting that the two WERE superadditive in > D-7, only that Metol appears to have a preservative effect > on the Pyro. But that's not the point of the previous post to which you responded. > I am not sure when the idea of superadditivity was > developed but it must have been pretty early on, maybe the > late 1920's. It seems to be a very old idea. The effect > might have been known and used well before a good > explanation of it existed just as the pH rise of D-76 was > known shortly after it was designed. Carlton and Crabtree > did not know what caused it but were able to deal with it. I > think you short change the knowledge of the past. The early observation of superadditivity goes back to c. 1890. But there was no agreement as to what was the mechanism of superadditivity until late 1940s. More definite answer had to wait for 1970s. Using empirical knowledge for engineering problems is different from scientific understanding of what is going on in the actual development process. The previous post to which you responded was concerned about the latter. Also, note the inconsistency between your statement about D-76 being superadditive here, and your post a few days ago saying hydroquinone in D-76 has no contribution. -- Ryuji Suzuki "Keep a good head and always carry a light camera." ============================================================================================================= To unsubscribe from this list, go to www.freelists.org and logon to your account (the same e-mail address and password you set-up when you subscribed,) and unsubscribe from there.