[pure-silver] Re: Bleach

  • From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx>
  • To: <pure-silver@xxxxxxxxxxxxx>
  • Date: Fri, 18 Dec 2009 01:24:47 -0800


----- Original Message ----- From: "Tim Rudman" <tim@xxxxxxxxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Thursday, December 17, 2009 10:45 AM
Subject: [pure-silver] Re: Bleach


Hello Alan,

The bleach used in sepia toning is potassium ferricyanide (not as awful as it sounds!) with an added halide or halides to facilitate redevelopment in
the toner. The halide is commonly potassium bromide.



For bleaching local areas of a print potassium ferricyanide is usually used without the bromide and is either mixed with or followed by fixer.



If the spot is black you will be more successful with an iodine bleach, which bleaches down to white whereas PF will leave a pale yellow brown.



If the spot is grey and needs lightening PF is excellent. If black it is easier to take to white with iodine and spot in afterwards.



Tim

Note that the iodine bleach needs to be followed by fixing as well. Even though Farmer's Reducer which is the potassium fericyanide bleach, contains fixer the finished print or negative should be refixed in regular fixer to insure no silver halide is left. If there is any it will eventually cause staining. Plain iodine as available from the drugstore works fine although you may want to dilute it with water or alcohol. It works quite rapidly. Household bleach, used full strength, will remove the emulsion completely. It has little, if any, use in photography other than as a cleaner.

--
Richard Knoppow
Los Angeles, CA, USA
dickburk@xxxxxxxxxxxxx
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