[pure-silver] Re: Mercury Intensifier (VMI): was Increasing Grain

  • From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx>
  • To: <pure-silver@xxxxxxxxxxxxx>
  • Date: Fri, 16 Jun 2006 13:04:11 -0700


----- Original Message ----- From: "Koch, Gerald" <gkoch02@xxxxxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Friday, June 16, 2006 6:24 AM
Subject: [pure-silver] Re: Mercury Intensifier (VMI): was Increasing Grain



VMI is said to increase contrast. If your negative is already contrasty
then this intensifier may not be the best choice. If the negative lacks
shadow detail then no amount of intensification will produce it. Have
you tried bleaching and redeveloping in a staining developer. From what
I have read this can be done a number of times to gain density.


Jerry

The image from a Mercury intensifier is not permanent. I don't know what the mechanism is but the warning is frequent in literature describing them.
A Mercury redeveloper can be used with bleaches other than Potassium cyanide. The amount of intensification is less but there is better intensification of the shadows. Monckhoven's Intensifier has the property of reducing the shadows while intensifying the denser areas. It was really meant for dot sharpening of half tone negatives.
There are other intensifiers which may be superior for a weak negative. Kodak recommends its Quinone-Thiosulfate intensifier, In-6. Kodak states that it gives the greatest amount of intensification of any single bath intensifier. However, the images are not permanent.
Bleach and redevelop Sepia toner will provide some intensification, however, the negative must be well washed since any residual hypo will form Farmer's reducer with the bleach bath.
Kodak Chromium intensifier, In-4, produces relatively long lived images. The bleach is a simple Dichromat bleach but uses Hydrochloric acid rather than Sulfuric acid. This results in generation of Silver Chloride rather than removing the silver.


Kodak In-4 Stock Solution

Potassium Bichromate                90.0 grams
Hydrochloric acid, concentrated     64.0 ml
Water to make                        1.0 liter

For use take 1 part bleach and 10 parts water.

Bleach thoroughly and wash for about 5 minutes in running water.
Redevelop in a low sulfite developer like D-72 (Dektol) diluted 1:3 for about 10 minutes. Carry out the redevelopment in room light but avoid direct daylight. Wash thoroughly after redeveloping.
The process can be repeated for greater intensification.


Intensifiers of all types increase contrast. They are mainly useful for properly exposed but underdeveloped negatives. Underexposed negatives will tend to have little or no shadow detail even when intensified.

If you are interested in the Kodak Quinone-Hypo or Kodak Silver intensifiers, and can not find them, I will post them to the list (lots of typing).

---
Richard Knoppow
Los Angeles, CA, USA
dickburk@xxxxxxxxxxxxx


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