[pure-silver] Re: Was Old paperandDefender... now The Hows and Whys Qiuz Show for Dummies: Whats the Mechanism?

  • From: Ray Rogers <earthsoda@xxxxxxxxx>
  • To: pure-silver@xxxxxxxxxxxxx
  • Date: Sat, 1 Mar 2008 23:16:19 -0800 (PST)

--- mail1 <mail1@xxxxxxxxxxxxxxxxx> wrote:

>each form of reduction has different formulations of reducers,
>and these differences change the mechanism of reduction. 


Jonathan,

Yes... 
and I have not looked at the problem from that side yet.
Obviously, that will help.
I will consult Mees (which edition do you have?) but I dont recall the 
mechanism of how the bleach
differentiates being addressed so I was just trying to think it through 
logically.

Ray


> >> The three classifications of reduction or the removal of 
> >> silver from the
> >> photographic image are.
> >> 1. Subtractive. Reducers of this type remove equal amounts 
> >> of silver from
> >> all densities there by increasing the density range of the 
> >> negative.
> >> Subtractive reducers improve over exposed negatives, and 
> >> positives, or for
> >> removing fog.
> >> 2. Proportional. Reducers of this type remove from each 
> >> density an amount of
> >> silver which is proportional to the original density. 
> >> Proportional reducers
> >> are a means of reducing excess density and contrast due to 
> >> overdevelopment.
> >>
> >> 3. Super Proportional. Reducers of this type remove a 
> >> greater proportion
> >> from the higher densities than the lower densities. This 
> >> type reduces
> >> density of overdeveloped negatives of contrasty subjects.
> >>
> >> Photographic reduction is a process of oxidation where the 
> >> reducer converts
> >> the metallic silver into a silver compound which is 
> >> soluble in water, in an
> >> acid, or other suitable solvent.

> >    These are good definitions but do not address the 
> >_mechanism_ by which the reducer discriminates density. I 
> >don't remember seeing this addressed in any of the theory 
> >books I have but it may well have been in newer 
> >publications. It just simply never occured to me to wonder 
> >about it before.
> >
> >---
> >Richard Knoppow



      
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