I happen to know a metallurgical scientist. Gordon, what do you think about this? Steve Smith ------------------------------------------- This is a forwarded message From: Bridgers, Gene <gbridger@xxxxxx> To: <rlandman@xxxxxxxxxxxxxxxxx>, "Leidecker, Henning W. \(GSFC-562.0\)" <henning.w.leidecker@xxxxxxxx>, "John Burke" <john@xxxxxxxxxxx> Date: Monday, March 24, 2008, 7:52:12 AM Subject: RoHS ===8<==============Original message text=============== Hello Bob, As I read the 760G specification sheet, the benefit described was to seal the connection area preventing humidity from getting to the area that is likely to degrade and produce fret corrosion debrie. I agree that keeping the humidity away is very helpful to reduce the rate of degredation. If you are going to select such materials with rapid degredation characterristics, you need to do more environmental protection. No argument from me. That protection will delay the fret corrosion for a longer time relative to what would exist very early without the environmental protection. I am not a metalurigical scientist, so I do not knoww the metalurigical acceleration factors for tin-tin versus 30 u inches gold-gold. I know you can wearout gold-gold with enough vibration. It has an end-of-life. I lose sleep when trying to walk a middle ground. I was very glad when Dr Dave decided on a specific path, since I could adopt his recommendation and then sleep soundly again. Regards, Gene ________________________________ From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Monday, March 24, 2008 10:06 AM To: Bridgers, Gene; Leidecker, Henning W. (GSFC-562.0); John Burke Cc: howie03@xxxxxxxxxx; Steve Smith Subject: RE: RoHS Gene, Sometimes theory and experimental evidence will lead to different conclusions. We had been chasing problems in the field with Molex tin plated power cable connectors (between boards in our product) that only seemed to occur in high humidity high temp environments where the switch gear shakes rather violently when it operates. It took a great deal of time to finally pin down this was the problem. The customer sent us pictures showing what looked to be discoloration on portions of the header pins on the boards. We called Molex and their engineering dept recommended specifically Nyogel lubricant> They said that all the automakers use it on every connection in vehicles, esp. hybrids, golf carts, any place the environment can be a factor. Needless to say 30u gold is preferrable, but in the industrial market (and in the case of the auto market (commercial market) prohibitively expensive. So we tried the lubricant at the customer and it's worked miracles. Intermittant problems disappeared 100%. It's a thick grease (proprietary formula) and we swear by it. We recommended it to some other customers having problems with other equipment and again it solved problems. One of the most vexing common problem is intermittant flashlights. Greasing the terminals of the batteries eliminates the problem. Even my HP 41CV calculator which has flexible gold plated fingers (which turn green) now are totally reliable with this lubricant. It seems to me that the air we breath today is so full of contaminants we need this kind of contact protection. (Info on the grease below) Bob We found a good price at BatteryJunction.com <http://www.batteryjunction.com/> Here's the page with the grease on it: http://www.batteryjunction.com/nyogel-760g.html Good article on the lubricant: http://www.machinedesign.com/ASP/strArticleID/56604/strSite/MDSite/viewS electedArticle.asp Nye wrote me: Bob: The 760G will really help prevent any further deterioration of the connector after application. Sincerely, Mark J. Coholan Technical Support Engineer Nye Lubricants, Inc. 12 Howland Rd. Fairhaven, MA 02719 Ph: 508.996.6721 Fx: 508.997.5285 Em:mcoholan@xxxxxxxxxxxxxxxxx http://www.nyelubricants.com <http://www.nyelubricants.com/> Learn more about the SmartGrease brand in this 3 minute video presentation: http://www.impactmovie.com/nye/ NYE LUBRICANTS The SmartGrease Company Bob ________________________________ From: Bridgers, Gene [mailto:gbridger@xxxxxx] To: rlandman@xxxxxxxxxxxxxxxxx, Leidecker, Henning W. (GSFC-562.0) [mailto:henning.w.leidecker@xxxxxxxx], John Burke [mailto:john@xxxxxxxxxxx] Cc: howie03@xxxxxxxxxx Sent: Mon, 24 Mar 2008 08:06:13 -0400 Subject: RE: RoHS Hi Bob, Somday, I will buy you lunch and share with you Dr David Steinberg's theory on contact lubricant. Dr Dave convinced me to avoid connector lubricants. Dr Dave pointed out that what ever debrie is created, is caught by the contact lubricant and it is then located just where it can do the most bad things. We do not allow contact lubrication to be used or the warranty is voided. Regards, Gene ________________________________ From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Sunday, March 23, 2008 12:48 PM To: Leidecker, Henning W. (GSFC-562.0); John Burke; Bridgers, Gene Cc: howie03@xxxxxxxxxx Subject: RE: RoHS thankfully we don't use fingers on our PC boards but we do use DB style connectors and I wonder if the microinches of gold on them has also been reduced. 1-2 insertions is more typical for our equipment as its normally installed and not removed unless the equipment fails. Have not seen any connector reliability problems except on an older product which had an AMP RJ-45 (telephone style jack). Green gunk would appear on the jack in Southern climes which means that there were pinholes in the coating and the copper(beryliium?) springy metal underneath had tarnished. Cleaning then coating with Nye contact lubricant eliminated future problems. Bob ________________________________ From: Leidecker, Henning W. (GSFC-562.0) [mailto:henning.w.leidecker@xxxxxxxx] To: rlandman@xxxxxxxxxxxxxxxxx, John Burke [mailto:john@xxxxxxxxxxx], Bridgers, Gene [mailto:gbridger@xxxxxx] Cc: howie03@xxxxxxxxxx Sent: Sat, 22 Mar 2008 21:54:01 -0400 Subject: RE: RoHS Dear Bob, Some years ago, just after gold jumped in cost again, the Pacific rim suppliers dropped the thickness of gold coating on the gold-coated fingers on the contacts of the Personal Computer plug-in cards from 30 micro-inches to 10 micro-inches. The USA gang followed this within hours, saying "competitive pressure" and "it must be OK". It took about two years for the reliability studies to be finished. The 10 micro-inch thick stuff was OK for about three mate/demate cycles, and was certainly worn out (= erratic in contacting) after 10 cycles. Also, pin-hole corrosion exploded in harm. The older 30 micro-inch was OK for about 200 cycles, and far less troubled by pin-hole corrosion. And by then, field use had confirmed terrible reliability problems with the thiner stuff. Sincerely, Henning -----Original Message----- From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Wed 3/19/2008 6:02 PM To: John Burke; Bridgers, Gene Cc: Leidecker, Henning W. (GSFC-562.0); howie03@xxxxxxxxxx Subject: RE: RoHS This is a company who supplies shields that are RoHS compliant http://www.lairdtech.com/pages/products/index.asp They are all MATTE TIN. Henning Leidecker at NASA commented: Matte tin, electroplated over steel, has a chance to develop whiskers at a density of between zero to 500 -- 1,000 whiskers per square centimeter; these would probably have a log-normal distribution of lengths with a median length growing at 0.3 to 1 mm per year, starting after perhaps 6 months. Bob Landman From: John Burke [mailto:john@xxxxxxxxxxx] Sent: Wednesday, March 19, 2008 4:26 PM To: 'Bridgers, Gene';rlandman@xxxxxxxxxxxxxxxxx Cc: Henning.W.Leidecker@xxxxxxxx;howie03@xxxxxxxxxx Subject: RE: RoHS Excellent!! Thank you.I am running several programes on RoHS 6 some for telecoms applications.. The interesting thing is that no one wants to do the tin whisker testing because of the time frame/cost, so they all point at their competition (larger ones) saying "well they (the competition company) must have done it and we use the same components so it must be OK".............8-( John Burke (408) 515 4992 From: Bridgers, Gene [mailto:gbridger@xxxxxx] Sent: Tuesday, March 18, 2008 6:08 PM To: rlandman@xxxxxxxxxxxxxxxxx Cc: Henning.W.Leidecker@xxxxxxxx; howie03@xxxxxxxxxx; john@xxxxxxxxxxx Subject: RE: RoHS Bob, Our local IEEE Reliability ADCOM met tonight and the attached proposal was made and approved. Gene From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Friday, January 18, 2008 11:13 AM To: Bridgers, Gene Cc: Henning.W.Leidecker@xxxxxxxx; howie03@xxxxxxxxxx; john@xxxxxxxxxxx Subject: RE: RoHS Excellent news Gene! I would very much like to be a part of this effort. I've copied this reply to Howie Johnson, Henning Leidecker and John Burke so they'll be aware of our efforts. Hopefully other IEEE groups will form to do likewise. Best regards, Bob From: Bridgers, Gene [mailto:gbridger@xxxxxx] Sent: Friday, January 18, 2008 8:16 AM To: rlandman@xxxxxxxxxxxxxxxxx Subject: RE: RoHS Bob, The day after we met, Craig Hillman visited us at Mercury and we discussed this risk in addition to other risks. I have made a proposal to our local IEEE to make thois topic a formal project. Next week, the leadership will meet and we should have clear marching orders in less than 1 month. Thanks, Gene PS, I start my vacation on Saturday but I will have some limited access to email. From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Thursday, January 17, 2008 11:25 AM To: naraway@xxxxxxxxxxxxxxxxx; Bridgers, Gene; pmccormack@xxxxxxxxxxxxxx; ramon.de-la-cruz@xxxxxxxxxxxx Cc: john@xxxxxxxxxxx Subject: RE: RoHS Bob Landman, President Senior Member, IEEE PES H&L Instruments, LLC (tel) 603-964-1818 www.hlinstruments.com Dear Nancy Naraway, (I've CC'd this reply to others who expressed a similar concern about the reliability issues with RoHS.) Thanks for the note re meeting you at the Boston IEEE Reliability seminar at EMC. I was pleased to see that many in the audience, besides the speaker (Dr. Craig Hillman of DfR Solutions) agrees with me that eliminating lead from solder was a mistake. So the question is, what can we do about it? Well, I'm not sure what we can do about RoHS but we have to try to do something. Our lives and the products we manufacture depend on there being at least 5% lead in solder (and in the solder plating of all electronic parts) to prevent tin whisker growth and provide joints that do not fracture due to temperature cycling. It is not an environmental problem - it is a problem in the heads of people who do not understand the chemistry of lead in solder. As John Burke (www.rohsusa.com) states: It is widely accepted in the engineering community that the recent ban of lead in solders for use in electronics in Europe is not only erroneous, but will actually lead to a worsening situation on the environment with the replacements being in general use from July '06 having a GREATER environmental impact. His source? - The US Environmental protection agency. The EPA report on Solders in Electronics: A Life-Cycle Assessment (472 pages) published August 2005 has some very interesting data. It shows that the replacements for "leaded" solder generally referred to as "SAC alloy" has a higher impact than tin lead solder in a number of areas such as: Non-renewable resource use Energy use Global warming Ozone depletion Water Quality for Environmentalists and Engineers everywhere here is the link: http://www.epa.gov/opptintr/dfe/pubs/solder/lca/index.htm To refer to such solder replacements as "Green" is laughable given the much greater impact on non-renewable resources (NRR). Check out tables ES-4 and ES-5 in the report. A quote from the report: "The difference between SAC (the replacement solder) and SnPb (the leaded solder) is 453 kg of NRR per 1,000 cc of solder applied. If this were all automotive gasoline, this difference is equivalent to 162 gallons of gasoline. Assuming a driver consumes 20 gallons per week, this is also equivalent to approximately 8 weeks of driving". =================== For now, I'd like to ask you all to please get acquainted (if you have not already done so) with the websites/articles (and share them with colleagues who are like-minded). We have to get the word out that RoHS is not a done deal - that we can turn back the clock and at least get 5% lead back in solder so we can eliminate tin whisker problems and joint reliability and solderability problems. I have a web folder with many articles on RoHS that you can reference and share with others http://hlinstruments.dnsalias.com/bob/RoHS/ CALCE has a website for Pb-free issues http://www.calce.umd.edu/lead-free/other/ CALCE also has a tin whiskers site http://www.calce.umd.edu/tin-whiskers/ NASA has a tin whiskers site with movies of whisker growth http://nepp.nasa.gov/WHISKER/ Also see http://nepp.nasa.gov/index_nasa.cfm/619/?id=E7C59CB3-E848-41DA-BC81C3607 CF0D1C2 ============================= Dr Henning Leidecker at NASA Goddard (Greenbelt Md) (one of my physics profs at AU) wrote me the following: Our world depends on the proper functioning of electronics, and so this is a world-wide problem. We already see eliminations of lead as causing failures in newly-produced electronics, and we can be sure we will see many more failures as the older equipment ages out of service and is replaced by this new lead-free stuff. Lives will surely be lost as a result, and probably already have been. But our systems are not set up to track this. Deaths are tracked at individual levels, but medical doctors assigning causes are not trained to report: "Cause of death was the failure of electronics, which in turn failed because the lead-free replacements did not work." Epidemic-tracking centers are set up to work with known diseases, and not deaths or injuries caused by equipment failing as a result of lead-free substitutes. Companies using the lead-free replacements are not (as far as I know) reporting any injuries or deaths caused by the failures of their equipment, caused by lead-free substitutions. I suppose they are more likely to settle any cases that are brought to their attention "out of court", which is to say, "out of the public's attention." Consider the failure of Galaxy IV, that silenced 35 million communication devices for about a day. Some of these devices were used by medical doctors. Can we suppose that there were NO cases of patient suffering (or worse) as a result of the loss of contact between patient and doctor? But who would track this? And make the findings publically available? And companies that suffer as their products fail as a result of use of leaded-tin substitutes are not tracked either. While the company remains in business, it is typically reluctant to advertise that it is suffering from such problems. If the company dies, then so too does the reason. No one tracks this cause. No one can say, "We lost 57 companies this year, as a result of failures due to the ill-performance of the leaded-tin substitutes." So we have a world-wide situation that is "under a basket", "out of the light', and likely to remain that way! One of the strong drivers for RoHS has been that people DO count the number of folks harmed by lead in their environment. But we do not count the number harmed by removing lead from electronics. So the situation is unbalanced. Thus, one way to go forward in achieving a better balance in RoHS actions, is to add "problems to people caused by failures of equipment caused by lead-free substitutes" to the problems noted by epidemic-tracking centers. Ditto for companies. ========= Another expert I was introduced to (Dr Howard Johnson, Signal Consulting www.sigcon.com -- High-Speed Digital Design seminars, publications and films) sent me this: When you pass around the article, please also reference the full EDN link with the associated video interview: http://www.edn.com/index.asp?layout=article&articleid=CA6477864 Video gets people's attention far more directly than any article ever could. In the film, Joe Fjeldstad (my interviewee) does a pretty good job of laying out the case that the RoHS lead-free initiative is bad for the environment, and bad for business. By the way, Joe has no objection to the other materials addressed by RoHS. He doesn't think the whole thing should be repealed, just the lead-in-solder part of it. ============= I received this from Dr. Howard Johnson Dear Dr. Johnson, I read your article about tin whisker problems and I thought I send you information about Corfin Industries and our ability to mitigate tin devices to SnPb devices. Please review the attached information on Corfin and feel free to contact me if you have any questions. Corfin Industries was a key player in a Navy MANTECH tin whisker study that proved Robotic Hot Solder Dip was an excellent process to remove pure tin and replace with tin lead. The other members of the study were Raytheon and the University of Maryland BMP lab. I have attached a copy of the report for you to review. Corfin Industries is an ISO certified trim, form and tinning facility. The three primary business functions are trim, form and tinning of fine pitch high reliability surface mount electronic devices, tinning of DIP's SIP's, PLCCs, LCCs, PGAs, RF Transistors, Connectors, TAB, Microwave and Hybrid devices and reclamation of product which is no longer solderable due to extended shelf life. We also provide tape and reeling, marking and lead reconditioning services. We service the Commercial, Military, Aerospace, Consumer Electronics and Telecommunications Industries. Our facility is certified to MIL-I-45208 and processes product to MIL-STD-2000A, MIL-M38510J, ANSI-J001 and MIL-PRF-38534. All Corfin Industries equipment are calibrated to MIL-STD-45662 and we maintain an ESD program to Mil-Std-1686. Our customers included Raytheon, BAE Systems, Lockheed- Martin and NASA to name a few. We will be happy to provide references upon request. Corfin Industries equipment utilizes nitrogen blanketing over the solder surface, thereby eliminating icicling and bridges. Please review the videos which show our equipment processing product at www.corfin.com. We also welcome visits to our facility in Salem, NH (about an hours drive from Boston) to review our processes. Please contact me with any questions you may have about Corfin Industries and our processes. Best Regards, Brian Gallagan From: Nancy Araway [mailto:naraway@xxxxxxxxxxxxxxxxx] Sent: Wednesday, January 09, 2008 9:48 PM To: rlandman@xxxxxxxxxxxxxxxxx Subject: Pleasure meeting you tonight Hello Bob, It was a pleasure meeting you this evening. You brought up some very interesting issues around RoHS and WeE. I'm attaching my resume only so you can get an idea of where I come from. I'm currently working a contract at Philips Medical, which very nicely leaves me open to do other consulting work. I have in the past worked on European Computer Manufactuurer's Assc. (ECMA), Computer and Business Equipment Manufacturer's Assc.(CBEMA), Telecom Industries Assc. (TIA), IEC and NFPA committees, authored the international standard for LAN safety and developed the presentation materials to influence an NFPA decision to rapidly cut in fast trip breakers. While none of them are recent, and it would require re-establishing contacts, I do know the processes and politics of the various standards making bodies. I also am experienced in the politics of working across the various European cultures. Based on my experience, I would focus on ECMA as a path to change the approach of the environmental standards. While I don't know if it can be done, I am quite sure that progress could be made through this organization. http://www.ecma-international.org/ While I realize that computers are not your focus, my rationale is that this organization has more impact on EC standards than any other that I know of. And it is currently European standards that are driving the environmental laws. The difficulty is that these regulations prey on people's fears, and they are spreading. It may be possible to sponsor a new ECMA committee focused on product reliability to address the impacts on reliability of the materials changes. On another front, a front page expose on USA Today of the cost of these regulations to businesses and users may be helpful in slowng down the adoption of them in the US. Do you know anyone that is tracking time to failure statistics on their product lines, and is seeing a significant decline since the lead free components have been introduced? I do know that Sycamore had that capability several years ago, but I don't know if they still do. Let me know if I can be of help. You can have some of my time. If travel is required, I will ask you to find someone to fund it. Nancy Araway Principle Consultant NAF Consulting ===8<===========End of original message text=========== -- Best regards, Steve Smith <steve@xxxxxxxxxxxxxxxxxxx> www.woodrestoration.com www.fiveyearclear.com www.smithandcompany.org, and especially www.smithandcompany.org/mwp/ http://www.lignu.com/lignu/tech_info/tech_info.php www.consultingscientist.us
--- Begin Message ---
- From: "Bridgers, Gene" <gbridger@xxxxxx>
- To: rlandman@xxxxxxxxxxxxxxxxx, "Leidecker, Henning W. (GSFC-562.0)" <henning.w.leidecker@xxxxxxxx>, "John Burke" <john@xxxxxxxxxxx>
- Date: Mon, 24 Mar 2008 10:52:12 -0400
Hello Bob, As I read the 760G specification sheet, the benefit described was to seal the connection area preventing humidity from getting to the area that is likely to degrade and produce fret corrosion debrie. I agree that keeping the humidity away is very helpful to reduce the rate of degredation. If you are going to select such materials with rapid degredation characterristics, you need to do more environmental protection. No argument from me. That protection will delay the fret corrosion for a longer time relative to what would exist very early without the environmental protection. I am not a metalurigical scientist, so I do not knoww the metalurigical acceleration factors for tin-tin versus 30 u inches gold-gold. I know you can wearout gold-gold with enough vibration. It has an end-of-life. I lose sleep when trying to walk a middle ground. I was very glad when Dr Dave decided on a specific path, since I could adopt his recommendation and then sleep soundly again. Regards, Gene ________________________________ From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Monday, March 24, 2008 10:06 AM To: Bridgers, Gene; Leidecker, Henning W. (GSFC-562.0); John Burke Cc: howie03@xxxxxxxxxx; Steve Smith Subject: RE: RoHS Gene, Sometimes theory and experimental evidence will lead to different conclusions. We had been chasing problems in the field with Molex tin plated power cable connectors (between boards in our product) that only seemed to occur in high humidity high temp environments where the switch gear shakes rather violently when it operates. It took a great deal of time to finally pin down this was the problem. The customer sent us pictures showing what looked to be discoloration on portions of the header pins on the boards. We called Molex and their engineering dept recommended specifically Nyogel lubricant> They said that all the automakers use it on every connection in vehicles, esp. hybrids, golf carts, any place the environment can be a factor. Needless to say 30u gold is preferrable, but in the industrial market (and in the case of the auto market (commercial market) prohibitively expensive. So we tried the lubricant at the customer and it's worked miracles. Intermittant problems disappeared 100%. It's a thick grease (proprietary formula) and we swear by it. We recommended it to some other customers having problems with other equipment and again it solved problems. One of the most vexing common problem is intermittant flashlights. Greasing the terminals of the batteries eliminates the problem. Even my HP 41CV calculator which has flexible gold plated fingers (which turn green) now are totally reliable with this lubricant. It seems to me that the air we breath today is so full of contaminants we need this kind of contact protection. (Info on the grease below) Bob We found a good price at BatteryJunction.com <http://www.batteryjunction.com/> Here's the page with the grease on it: http://www.batteryjunction.com/nyogel-760g.html Good article on the lubricant: http://www.machinedesign.com/ASP/strArticleID/56604/strSite/MDSite/viewS electedArticle.asp Nye wrote me: Bob: The 760G will really help prevent any further deterioration of the connector after application. Sincerely, Mark J. Coholan Technical Support Engineer Nye Lubricants, Inc. 12 Howland Rd. Fairhaven, MA 02719 Ph: 508.996.6721 Fx: 508.997.5285 Em:mcoholan@xxxxxxxxxxxxxxxxx http://www.nyelubricants.com <http://www.nyelubricants.com/> Learn more about the SmartGrease brand in this 3 minute video presentation: http://www.impactmovie.com/nye/ NYE LUBRICANTS The SmartGrease Company Bob ________________________________ From: Bridgers, Gene [mailto:gbridger@xxxxxx] To: rlandman@xxxxxxxxxxxxxxxxx, Leidecker, Henning W. (GSFC-562.0) [mailto:henning.w.leidecker@xxxxxxxx], John Burke [mailto:john@xxxxxxxxxxx] Cc: howie03@xxxxxxxxxx Sent: Mon, 24 Mar 2008 08:06:13 -0400 Subject: RE: RoHS Hi Bob, Somday, I will buy you lunch and share with you Dr David Steinberg's theory on contact lubricant. Dr Dave convinced me to avoid connector lubricants. Dr Dave pointed out that what ever debrie is created, is caught by the contact lubricant and it is then located just where it can do the most bad things. We do not allow contact lubrication to be used or the warranty is voided. Regards, Gene ________________________________ From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Sunday, March 23, 2008 12:48 PM To: Leidecker, Henning W. (GSFC-562.0); John Burke; Bridgers, Gene Cc: howie03@xxxxxxxxxx Subject: RE: RoHS thankfully we don't use fingers on our PC boards but we do use DB style connectors and I wonder if the microinches of gold on them has also been reduced. 1-2 insertions is more typical for our equipment as its normally installed and not removed unless the equipment fails. Have not seen any connector reliability problems except on an older product which had an AMP RJ-45 (telephone style jack). Green gunk would appear on the jack in Southern climes which means that there were pinholes in the coating and the copper(beryliium?) springy metal underneath had tarnished. Cleaning then coating with Nye contact lubricant eliminated future problems. Bob ________________________________ From: Leidecker, Henning W. (GSFC-562.0) [mailto:henning.w.leidecker@xxxxxxxx] To: rlandman@xxxxxxxxxxxxxxxxx, John Burke [mailto:john@xxxxxxxxxxx], Bridgers, Gene [mailto:gbridger@xxxxxx] Cc: howie03@xxxxxxxxxx Sent: Sat, 22 Mar 2008 21:54:01 -0400 Subject: RE: RoHS Dear Bob, Some years ago, just after gold jumped in cost again, the Pacific rim suppliers dropped the thickness of gold coating on the gold-coated fingers on the contacts of the Personal Computer plug-in cards from 30 micro-inches to 10 micro-inches. The USA gang followed this within hours, saying "competitive pressure" and "it must be OK". It took about two years for the reliability studies to be finished. The 10 micro-inch thick stuff was OK for about three mate/demate cycles, and was certainly worn out (= erratic in contacting) after 10 cycles. Also, pin-hole corrosion exploded in harm. The older 30 micro-inch was OK for about 200 cycles, and far less troubled by pin-hole corrosion. And by then, field use had confirmed terrible reliability problems with the thiner stuff. Sincerely, Henning -----Original Message----- From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Wed 3/19/2008 6:02 PM To: John Burke; Bridgers, Gene Cc: Leidecker, Henning W. (GSFC-562.0); howie03@xxxxxxxxxx Subject: RE: RoHS This is a company who supplies shields that are RoHS compliant http://www.lairdtech.com/pages/products/index.asp They are all MATTE TIN. Henning Leidecker at NASA commented: Matte tin, electroplated over steel, has a chance to develop whiskers at a density of between zero to 500 -- 1,000 whiskers per square centimeter; these would probably have a log-normal distribution of lengths with a median length growing at 0.3 to 1 mm per year, starting after perhaps 6 months. Bob Landman From: John Burke [mailto:john@xxxxxxxxxxx] Sent: Wednesday, March 19, 2008 4:26 PM To: 'Bridgers, Gene';rlandman@xxxxxxxxxxxxxxxxx Cc: Henning.W.Leidecker@xxxxxxxx;howie03@xxxxxxxxxx Subject: RE: RoHS Excellent!! Thank you.I am running several programes on RoHS 6 some for telecoms applications.. The interesting thing is that no one wants to do the tin whisker testing because of the time frame/cost, so they all point at their competition (larger ones) saying "well they (the competition company) must have done it and we use the same components so it must be OK".............8-( John Burke (408) 515 4992 From: Bridgers, Gene [mailto:gbridger@xxxxxx] Sent: Tuesday, March 18, 2008 6:08 PM To: rlandman@xxxxxxxxxxxxxxxxx Cc: Henning.W.Leidecker@xxxxxxxx; howie03@xxxxxxxxxx; john@xxxxxxxxxxx Subject: RE: RoHS Bob, Our local IEEE Reliability ADCOM met tonight and the attached proposal was made and approved. Gene From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Friday, January 18, 2008 11:13 AM To: Bridgers, Gene Cc: Henning.W.Leidecker@xxxxxxxx; howie03@xxxxxxxxxx; john@xxxxxxxxxxx Subject: RE: RoHS Excellent news Gene! I would very much like to be a part of this effort. I've copied this reply to Howie Johnson, Henning Leidecker and John Burke so they'll be aware of our efforts. Hopefully other IEEE groups will form to do likewise. Best regards, Bob From: Bridgers, Gene [mailto:gbridger@xxxxxx] Sent: Friday, January 18, 2008 8:16 AM To: rlandman@xxxxxxxxxxxxxxxxx Subject: RE: RoHS Bob, The day after we met, Craig Hillman visited us at Mercury and we discussed this risk in addition to other risks. I have made a proposal to our local IEEE to make thois topic a formal project. Next week, the leadership will meet and we should have clear marching orders in less than 1 month. Thanks, Gene PS, I start my vacation on Saturday but I will have some limited access to email. From: Bob Landman [mailto:rlandman@xxxxxxxxxxxxxxxxx] Sent: Thursday, January 17, 2008 11:25 AM To: naraway@xxxxxxxxxxxxxxxxx; Bridgers, Gene; pmccormack@xxxxxxxxxxxxxx; ramon.de-la-cruz@xxxxxxxxxxxx Cc: john@xxxxxxxxxxx Subject: RE: RoHS Bob Landman, President Senior Member, IEEE PES H&L Instruments, LLC (tel) 603-964-1818 www.hlinstruments.com Dear Nancy Naraway, (I've CC'd this reply to others who expressed a similar concern about the reliability issues with RoHS.) Thanks for the note re meeting you at the Boston IEEE Reliability seminar at EMC. I was pleased to see that many in the audience, besides the speaker (Dr. Craig Hillman of DfR Solutions) agrees with me that eliminating lead from solder was a mistake. So the question is, what can we do about it? Well, I'm not sure what we can do about RoHS but we have to try to do something. Our lives and the products we manufacture depend on there being at least 5% lead in solder (and in the solder plating of all electronic parts) to prevent tin whisker growth and provide joints that do not fracture due to temperature cycling. It is not an environmental problem - it is a problem in the heads of people who do not understand the chemistry of lead in solder. As John Burke (www.rohsusa.com) states: It is widely accepted in the engineering community that the recent ban of lead in solders for use in electronics in Europe is not only erroneous, but will actually lead to a worsening situation on the environment with the replacements being in general use from July '06 having a GREATER environmental impact. His source? - The US Environmental protection agency. The EPA report on Solders in Electronics: A Life-Cycle Assessment (472 pages) published August 2005 has some very interesting data. It shows that the replacements for "leaded" solder generally referred to as "SAC alloy" has a higher impact than tin lead solder in a number of areas such as: Non-renewable resource use Energy use Global warming Ozone depletion Water Quality for Environmentalists and Engineers everywhere here is the link: http://www.epa.gov/opptintr/dfe/pubs/solder/lca/index.htm To refer to such solder replacements as "Green" is laughable given the much greater impact on non-renewable resources (NRR). Check out tables ES-4 and ES-5 in the report. A quote from the report: "The difference between SAC (the replacement solder) and SnPb (the leaded solder) is 453 kg of NRR per 1,000 cc of solder applied. If this were all automotive gasoline, this difference is equivalent to 162 gallons of gasoline. Assuming a driver consumes 20 gallons per week, this is also equivalent to approximately 8 weeks of driving". =================== For now, I'd like to ask you all to please get acquainted (if you have not already done so) with the websites/articles (and share them with colleagues who are like-minded). We have to get the word out that RoHS is not a done deal - that we can turn back the clock and at least get 5% lead back in solder so we can eliminate tin whisker problems and joint reliability and solderability problems. I have a web folder with many articles on RoHS that you can reference and share with others http://hlinstruments.dnsalias.com/bob/RoHS/ CALCE has a website for Pb-free issues http://www.calce.umd.edu/lead-free/other/ CALCE also has a tin whiskers site http://www.calce.umd.edu/tin-whiskers/ NASA has a tin whiskers site with movies of whisker growth http://nepp.nasa.gov/WHISKER/ Also see http://nepp.nasa.gov/index_nasa.cfm/619/?id=E7C59CB3-E848-41DA-BC81C3607 CF0D1C2 ============================= Dr Henning Leidecker at NASA Goddard (Greenbelt Md) (one of my physics profs at AU) wrote me the following: Our world depends on the proper functioning of electronics, and so this is a world-wide problem. We already see eliminations of lead as causing failures in newly-produced electronics, and we can be sure we will see many more failures as the older equipment ages out of service and is replaced by this new lead-free stuff. Lives will surely be lost as a result, and probably already have been. But our systems are not set up to track this. Deaths are tracked at individual levels, but medical doctors assigning causes are not trained to report: "Cause of death was the failure of electronics, which in turn failed because the lead-free replacements did not work." Epidemic-tracking centers are set up to work with known diseases, and not deaths or injuries caused by equipment failing as a result of lead-free substitutes. Companies using the lead-free replacements are not (as far as I know) reporting any injuries or deaths caused by the failures of their equipment, caused by lead-free substitutions. I suppose they are more likely to settle any cases that are brought to their attention "out of court", which is to say, "out of the public's attention." Consider the failure of Galaxy IV, that silenced 35 million communication devices for about a day. Some of these devices were used by medical doctors. Can we suppose that there were NO cases of patient suffering (or worse) as a result of the loss of contact between patient and doctor? But who would track this? And make the findings publically available? And companies that suffer as their products fail as a result of use of leaded-tin substitutes are not tracked either. While the company remains in business, it is typically reluctant to advertise that it is suffering from such problems. If the company dies, then so too does the reason. No one tracks this cause. No one can say, "We lost 57 companies this year, as a result of failures due to the ill-performance of the leaded-tin substitutes." So we have a world-wide situation that is "under a basket", "out of the light', and likely to remain that way! One of the strong drivers for RoHS has been that people DO count the number of folks harmed by lead in their environment. But we do not count the number harmed by removing lead from electronics. So the situation is unbalanced. Thus, one way to go forward in achieving a better balance in RoHS actions, is to add "problems to people caused by failures of equipment caused by lead-free substitutes" to the problems noted by epidemic-tracking centers. Ditto for companies. ========= Another expert I was introduced to (Dr Howard Johnson, Signal Consulting www.sigcon.com -- High-Speed Digital Design seminars, publications and films) sent me this: When you pass around the article, please also reference the full EDN link with the associated video interview: http://www.edn.com/index.asp?layout=article&articleid=CA6477864 Video gets people's attention far more directly than any article ever could. In the film, Joe Fjeldstad (my interviewee) does a pretty good job of laying out the case that the RoHS lead-free initiative is bad for the environment, and bad for business. By the way, Joe has no objection to the other materials addressed by RoHS. He doesn't think the whole thing should be repealed, just the lead-in-solder part of it. ============= I received this from Dr. Howard Johnson Dear Dr. Johnson, I read your article about tin whisker problems and I thought I send you information about Corfin Industries and our ability to mitigate tin devices to SnPb devices. Please review the attached information on Corfin and feel free to contact me if you have any questions. Corfin Industries was a key player in a Navy MANTECH tin whisker study that proved Robotic Hot Solder Dip was an excellent process to remove pure tin and replace with tin lead. The other members of the study were Raytheon and the University of Maryland BMP lab. I have attached a copy of the report for you to review. Corfin Industries is an ISO certified trim, form and tinning facility. The three primary business functions are trim, form and tinning of fine pitch high reliability surface mount electronic devices, tinning of DIP's SIP's, PLCCs, LCCs, PGAs, RF Transistors, Connectors, TAB, Microwave and Hybrid devices and reclamation of product which is no longer solderable due to extended shelf life. We also provide tape and reeling, marking and lead reconditioning services. We service the Commercial, Military, Aerospace, Consumer Electronics and Telecommunications Industries. Our facility is certified to MIL-I-45208 and processes product to MIL-STD-2000A, MIL-M38510J, ANSI-J001 and MIL-PRF-38534. All Corfin Industries equipment are calibrated to MIL-STD-45662 and we maintain an ESD program to Mil-Std-1686. Our customers included Raytheon, BAE Systems, Lockheed- Martin and NASA to name a few. We will be happy to provide references upon request. Corfin Industries equipment utilizes nitrogen blanketing over the solder surface, thereby eliminating icicling and bridges. Please review the videos which show our equipment processing product at www.corfin.com. We also welcome visits to our facility in Salem, NH (about an hours drive from Boston) to review our processes. Please contact me with any questions you may have about Corfin Industries and our processes. Best Regards, Brian Gallagan From: Nancy Araway [mailto:naraway@xxxxxxxxxxxxxxxxx] Sent: Wednesday, January 09, 2008 9:48 PM To: rlandman@xxxxxxxxxxxxxxxxx Subject: Pleasure meeting you tonight Hello Bob, It was a pleasure meeting you this evening. You brought up some very interesting issues around RoHS and WeE. I'm attaching my resume only so you can get an idea of where I come from. I'm currently working a contract at Philips Medical, which very nicely leaves me open to do other consulting work. I have in the past worked on European Computer Manufactuurer's Assc. (ECMA), Computer and Business Equipment Manufacturer's Assc.(CBEMA), Telecom Industries Assc. (TIA), IEC and NFPA committees, authored the international standard for LAN safety and developed the presentation materials to influence an NFPA decision to rapidly cut in fast trip breakers. While none of them are recent, and it would require re-establishing contacts, I do know the processes and politics of the various standards making bodies. I also am experienced in the politics of working across the various European cultures. Based on my experience, I would focus on ECMA as a path to change the approach of the environmental standards. While I don't know if it can be done, I am quite sure that progress could be made through this organization. http://www.ecma-international.org/ While I realize that computers are not your focus, my rationale is that this organization has more impact on EC standards than any other that I know of. And it is currently European standards that are driving the environmental laws. The difficulty is that these regulations prey on people's fears, and they are spreading. It may be possible to sponsor a new ECMA committee focused on product reliability to address the impacts on reliability of the materials changes. On another front, a front page expose on USA Today of the cost of these regulations to businesses and users may be helpful in slowng down the adoption of them in the US. Do you know anyone that is tracking time to failure statistics on their product lines, and is seeing a significant decline since the lead free components have been introduced? I do know that Sycamore had that capability several years ago, but I don't know if they still do. Let me know if I can be of help. You can have some of my time. If travel is required, I will ask you to find someone to fund it. Nancy Araway Principle Consultant NAF Consulting
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