[pure-silver] Re: [pure-silver]Farmer Reducer was: Re: Ansco 221 Observations & Questions
- From: "Richard Knoppow" <dickburk@xxxxxxxxxxxxx>
- To: <pure-silver@xxxxxxxxxxxxx>
- Date: Mon, 11 Jun 2007 20:49:30 -0700
----- Original Message -----
From: <C.Breukel@xxxxxxx>
To: <pure-silver@xxxxxxxxxxxxx>
Sent: Monday, June 11, 2007 1:45 AM
Subject: [pure-silver] Re: [pure-silver]Farmer Reducer was:
Re: Ansco 221 Observations & Questions
Hi,
All this talk about bleaching made me wonder about the
following: in the
mentioned bleaches there is usual Potassiumferricyanide
(KFCN) and a
salt as PotassiumBromide, in order to convert the silver
salt back to
it's halide.
When you bleach with Farmer (KFCN and fixer) there is no
salt present,
so in what the silver atom is converted, into a
silver-ferricyanide
salt?
Best,
Cor
I am not sure of the chemistry. Evidently, the reducer
converts the silver to something that hypo will remove but
will not redevelop in a sulfide solution. The halide, of
course, will also dissolve in hypo.
---
Richard Knoppow
Los Angeles, CA, USA
dickburk@xxxxxxxxxxxxx
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