[neact] Re: More on HS chlorate explosion

  • From: Lois Ongley <longley@xxxxxxxxx>
  • To: "neact@xxxxxxxxxxxxx" <neact@xxxxxxxxxxxxx>
  • Date: Fri, 22 Jan 2010 17:00:22 -0500

Speculation would indicate that it was just potassium chlorate heated with 
stick of gum dropped in. A common enough HS experiment on You tube as gummi 
bear sacrifice.

Lois Ongley

From: neact-bounce@xxxxxxxxxxxxx [mailto:neact-bounce@xxxxxxxxxxxxx] On Behalf 
Of Kenneth Bowers
Sent: Friday, January 22, 2010 4:49 PM
To: neact@xxxxxxxxxxxxx
Subject: [neact] Re: More on HS chlorate explosion

I have conducted what I believe is the same experiment many times.

I always have done the experiment outside.

Can you provide more information on the catalyst used ?

Was concentrated sulfuric acid part of the experiment ?

Retired now from full time teaching. I still work on a regulart basis as a 
substitute.


                                                                                
                                                                                
        Kenneth Bowers
On Jan 22, 2010, at 12:22 PM, Stephen Stepenuck wrote:


Some follow-up info on the high school potassium chlorate explosion.  This too 
is from the ACS Division of Chemical Health and Safety's email list.
This account seems to me to be a strong argument for purchase and use of 
portable safety shields, and long heavy gloves for the teacher.

[Apologies for accidental post earlier.  Maybe when I'm 137 I'll learn to 
triple-check the address line...]
Steve
* * * * * * *
New York

http://www.dailyfreeman.com/articles/2010/01/21/news/doc4b57e5a7a5748273921860.txt

Teacher recovering; cause of blast uncertain
Published: Thursday, January 21, 2010

By JAY BRAMAN JR.
Correspondent

BOICEVILLE - The explosion on Tuesday that injured an Onteora High School 
chemistry teacher and seven of his students came as a surprise to everyone, but 
probably no one more than the longtime teacher himself.

Donald Bucher was demonstrating an experiment with the chemical potassium 
chlorate when the explosion - which was strong enough to damage a window in the 
classroom - occurred. Onteora school district Superintendent Leslie Ford said 
on Wednesday that Bucher had conducted the same experiment dozens of times 
before, without incident, and that the cause of the explosion remained a 
mystery.

Ford said Bucher was resting at home on Wednesday, recovering from his injury, 
and that an investigation of the incident will begin shortly.

"We still don't know what happened," the superintendent said. "But we will 
debrief Mr. Bucher when he is well enough to return."

Ford said a small piece of glass punctured Bucher's arm and cut an artery. "He 
was bleeding quite a lot," she said.

A reporter's calls to Bucher's home were not answered on Wednesday.

The seven students who were injured, all 11th-graders, were treated at Kingston 
and Benedictine hospitals, primarily for minor cuts, and released.

Ford said the explosion occurred when Bucher dropped a stick of gum into a test 
tube containing potassium chlorate, a chemical used in matches, explosives, 
gunpowder and fireworks.

Ford said school district officials reviewed the chemistry class' lesson plan 
and concluded the experiment had been performed safely by Bucher in the past. 
She also said it is a standard high school chemistry experiment and that Bucher 
executed each of its steps properly on Wednesday.

"The goal of the experiment was to determine the amount of oxygen in the 
potassium chlorate," Ford said.

The superintendent said possible causes of the accident were a faulty test tube 
or the chemical itself being compromised.

All the remaining potassium chlorate in the classroom was removed, bagged 
locked in a secure location elsewhere in the building by Michael O'Rourke of 
the Risk Management Department at Ulster BOCES, Ford said.

O'Rourke said on Wednesday that the chemical will be disposed of properly and 
other chemicals in the school will be checked for problems.

According to a Web site co-maintained by the National Oceanic and Atmospheric 
Administration, potassium chlorate is a white crystalline solid. It is used in 
matches, explosives, gunpowder and fireworks; as a disinfectant; and as an 
oxidizing agent. It forms a flammable mixture with combustible materials, and 
the mixture can be explosive if combustible material is finely divided.

Potassium chlorate can be ignited by friction, and contact with strong sulfuric 
acid may cause fires or explosions, according to the Web site. Also, it may 
spontaneously decompose and ignite when mixed with ammonium salts and may 
explode under prolonged exposure to heat or fire.

Ulster County Emergency Management Director Art Snyder appeared before the 
Onterora Board of Education during the body's regularly scheduled meeting 
Tuesday evening. He outlined the procedures for hazardous materials disposal, 
though Ford noted the procedures were not required in Tuesday's incident.

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